Preparation and applications of the tertiary copolymer poly(ethylene glycol) methacrylate/methyl methacrylate/diethyl allylphosphonate

被引：0
|
作者：
Li, Shenzhe [1 ]
Wang, Jikui [1 ,2 ]
Li, Yinyin [1 ]
Wu, Genhua [2 ]
Wang, Yuming [1 ]
Wang, Wenqi [1 ]
Guo, Jiahong [1 ]
机构：
[1] Key Laboratory for the Preparation and Application of Ultrafine Materials (Ministry of Education), School of Material Science and Engineering, East China University of Science and Technology, Shanghai,200237, China
[2] Collaborative Innovation Center for Petrochemical New Materials, Anqing,Anhui,246011, China
来源：
Journal of Applied Polymer Science | 2016年 / 133卷 / 44期
关键词：
A novel poly(acrylonitrile-co-butadiene-co-styrene) (ABS) antistatic and flame-retardant agent; poly(ethylene glycol) methacrylate/methyl methacrylate/diethyl allylphosphonate (PMMD); was synthesized from poly(ethylene glycol) methacrylate; methyl methacrylate; and diethyl allylphosphonate by free-radical precipitation polymerization in the aqueous phase to improve the antistatic and flame-retardant performance at the same time. Through adjustments of the molar ratios of the three monomers; various antistatic; flame-retardant copolymers (PMMD) were synthesized. The molecular structure and thermal stability of PMMD were analyzed with Fourier transform infrared spectroscopy and thermogravimetric analysis. The electrical resistivity and flame-retardant and mechanical properties of the ABS/PMMD composites were analyzed by a ZC90 megohmmeter; an oxygen index meter; a vertical burning tester; a memory impact testing machine; and a tensile testing machine. The morphology of PMMD in the ABS blends was characterized with scanning electron microscopy. The compatibilities of PMMD and ABS were characterized by the calculation of the thermodynamic work of adhesion via the measurement of the contact angle. The results show that the antistatic and flame-retardant performance of ABS were greatly improved by the PMMD copolymer and the mechanical properties of ABS showed little reduction. © 2016 Wiley Periodicals; Inc; J; Appl; Polym; Sci; 2016; 133; 44126. © 2016 Wiley Periodicals;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
相关论文
共 50 条
  • [1] Preparation and applications of the tertiary copolymer poly(ethylene glycol) methacrylate/methyl methacrylate/diethyl allylphosphonate
    Li, Shenzhe
    Wang, Jikui
    Li, Yinyin
    Wu, Genhua
    Wang, Yuming
    Wang, Wenqi
    Guo, Jiahong
    JOURNAL OF APPLIED POLYMER SCIENCE, 2016, 133 (44)
  • [2] Crystallization of Poly (ethylene glycol) in Poly (methyl methacrylate) Networks
    Li, Yong
    Ma, Qiuhua
    Huang, Caiyi
    Liu, Guoqin
    MATERIALS SCIENCE-MEDZIAGOTYRA, 2013, 19 (02): : 147 - 151
  • [3] Poly(methyl methacrylate)/poly(ethylene glycol)/poly(ethylene glycol dimethacrylate) micelles: Preparation, characterization, and application as doxorubicin carriers
    Yu, L. (yulili0218@gmail.com), 1600, John Wiley and Sons Inc (131):
  • [4] Poly(methyl methacrylate)/Poly(ethylene glycol)/Poly(ethylene glycol dimethacrylate) Micelles: Preparation, Characterization, and Application as Doxorubicin Carriers
    Yu, Lili
    Yao, Lin
    You, Jing
    Guo, Yihui
    Yang, Liyan
    JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (01)
  • [5] THERMOMECHANICAL BEHAVIOR OF POLY(ETHYLENE GLYCOL METHACRYLATE) AND POLY(DIETHYLENE GLYCOL METHACRYLATE)
    ILAVSKY, M
    SLONIMSKII, GL
    JANACEK, J
    JOURNAL OF POLYMER SCIENCE PART C-POLYMER SYMPOSIUM, 1967, (16PC): : 329 - +
  • [6] Graft copolymer electrolytes for high temperature Li-battery applications, using poly(methyl methacrylate) grafted poly(ethylene glycol)methyl ether methacrylate and lithium bis(trifluoromethanesulfonimide)
    Bergman, Martin
    Bergfelt, Andreas
    Sun, Bing
    Bowden, Tim
    Brandell, Daniel
    Johansson, Patrik
    ELECTROCHIMICA ACTA, 2015, 175 : 96 - 103
  • [7] Sulfonated poly(ethylene glycol) containing methacrylate copolymer surfaces;: Preparation, characterization and in vitro biocompatibility
    Park, KD
    Park, HD
    Lee, HJ
    Kim, YH
    Ooya, T
    Yui, N
    MACROMOLECULAR RESEARCH, 2004, 12 (04) : 342 - 351
  • [8] Preparation and Characterization of Novel Crosslinked Poly[glycidyl methacrylate-poly(ethylene glycol) methyl ether methacrylate] as Gel Polymer Electrolytes
    Luo, Dan
    Li, Yang
    Yang, Mujie
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 120 (05) : 2979 - 2984
  • [9] Poly(butyl methacrylate-g-methoxypoly(ethylene glycol)) and poly(methyl methacrylate-g-methoxypoly(ethylene glycol)) graft copolymers: preparation and aqueous solution properties
    Horgan, A
    Saunders, B
    Vincent, B
    Heenan, RK
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 262 (02) : 548 - 559
  • [10] Quantitative study of methyl methacrylate poly(ethylene glycol) methacrylate copolymer films using high mass resolution ToF-SIMS
    Briggs, D
    Davies, MC
    SURFACE AND INTERFACE ANALYSIS, 1997, 25 (09) : 725 - 733
12345