Aminophosphonium organocatalysts for the ring-opening copolymerisation of epoxide and cyclic anhydride

被引：1

作者：

Clark, Ella F. ^{[1
]}

Dunstan, Estelle ^{[1
]}

Kociok-Kohn, Gabriele ^{[2
]}

Buchard, Antoine ^{[3
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, England

[2] Univ Bath, Mat & Chem Characterisat Facil, Bath, England

[3] Univ York, Dept Chem, York YO10 5DD, England

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 89期

关键词：

ALTERNATING COPOLYMERIZATION; PHTHALIC-ANHYDRIDE; CARBON-DIOXIDE; POLYESTERS; OXIDE; POLYMERIZATION; PORPHYRIN; CATALYSTS; ROCOP;

D O I：

10.1039/d4cc03947e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Kirsanov reaction has been used to synthesise air stable, efficient and selective bifunctional aminophosphonium catalysts for the alternating ring-opening copolymerisation of cyclohexene oxide and phthalic anhydride without the need for a co-initiator. The Kirsanov reaction has been used to synthesise air stable, efficient and selective bifunctional aminophosphonium catalysts for the alternating ring-opening copolymerisation (ROCOP) of CHO/PA without the need for a co-initiator.

引用

页码：13067 / 13070

页数：4

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