Rhodium-catalyzed synthesis of Si-stereogenic alkoxysilanes and silyl enol ethers via hydrosilylation of carbonyl compounds

被引：1
|
作者：
Ding, Yang [1 ,2 ]
Ke, Jie [1 ,2 ]
Zhang, Wenbin [4 ]
Li, Bin [3 ]
He, Chuan [1 ,2 ]
机构：
[1] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China
[2] Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China
[3] Wuyi Univ, Sch Environm & Chem Engn, Jiangmen 529020, Guangdong, Peoples R China
[4] Guangdong Wamo New Mat Technol CO LTD, Jiangmen 529020, Guangdong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 93期
基金：
中国国家自然科学基金;
关键词：
ASYMMETRIC HYDROSILYLATION; SILICON; KETONES; CONSTRUCTION; SILANES; IMINES;
D O I：
10.1039/d4cc05360e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly efficient rhodium-catalyzed asymmetric hydrosilylation of aldehydes, ketones, and alpha,beta-unsaturated ketones with dihydrosilanes is developed, that allows the rapid assembly of a variety of Si-stereogenic alkoxysilanes and silyl enol ethers in good yields and enantioselectivities under mild conditions. The applicability of this methodology was demonstrated by a series of stereospecific transformations to construct diverse Si-stereogenic derivatives.
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页码：13734 / 13737
页数：4
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