Morphology and Physical-Chemical Properties of Composite Materials Based on Polyolefins and Chitosan

The introduction of hydrophilic fillers in the matrix of hydrophobic thermoplastic polymers is a complicated issue, due to thermodynamic incompatibility of the components and poor adhesion properties. These complications are the most pronounced in the case of a hydrophilic polymer which cannot melt without decomposition (as polysaccharides) used as the filler. In this study, we have taken advantage of the solvent-free extrusion method both to modify the chitosan chemical structure in order to impart amphiphilic properties and to mix the obtained derivatives with polyethylene. The influence of the processes parameters, the presence of plasticizer, and the filler content on the thermal and mechanical properties of the composite film materials as well as their morphology has been investigated. It has been found that the introduction of hydrophobic fragments in the structure of chitosan insignificantly improved the mechanical properties of the materials in comparison with the pristine polysaccharide. A more significant effect has been caused by simultaneous introduction of the plasticizer, affording the materials with uniform morphology and improved plasticity. © Pleiades Publishing, Ltd. 2024.