Chemical sensors - Nanoclay - Nitrogen oxides - Semiconductor doping;
D O I:
10.1039/d4nj04799k
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The real-time detection of noxious gases such as triethylamine (TEA) and xylene is important for human and environmental safety. In this work, Fe-NiO nanostructures with different doping concentrations were synthesized. By doping Fe, the gas sensitivity of NiO nanostructures was significantly improved. Gas-sensitive performance test results show that 0.93 at% Fe-NiO nanostructure-based sensors have more potential for TEA and xylene detection. The 0.93 at% Fe-NiO nanostructure-based sensor displays the highest response value of 38-50 ppm TEA at a working temperature of 220 degrees C and 18-50 ppm xylene at an operating temperature of 250 degrees C. Furthermore, the sensors show outstanding selectivity, stability and repeatability. The enhanced sensing characteristics can be ascribed to the doping of Fe with more oxygen vacancies. The as-prepared Fe-NiO nanostructures provide a novel dual-selectivity method for detection of TEA and xylene. In addition, the sensing mechanism was studied.
机构:
King Saud Univ, Coll Pharm, Dept Pharmacognosy, Riyadh 11451, Saudi ArabiaPukyong Natl Univ, New Senior Oriented Smart Hlth Care Educ Ctr, Busan 48513, South Korea
Alajmi, Mohamed F.
Alam, Shamshad
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机构:
Roswell Pk Canc Inst, Dept Pharmacol & Therapeut, Buffalo, NY 14263 USAPukyong Natl Univ, New Senior Oriented Smart Hlth Care Educ Ctr, Busan 48513, South Korea
Alam, Shamshad
Bhat, Kiesar Sideeq
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机构:
Univ Kashmir, Dept Bioresources, Srinagar 190006, IndiaPukyong Natl Univ, New Senior Oriented Smart Hlth Care Educ Ctr, Busan 48513, South Korea
Bhat, Kiesar Sideeq
Mishra, Prabhash
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机构:
Jamia Millia Islamia, Cent Univ, Fac Engn & Technol, Quantum Mat & Devices Lab, New Delhi 110025, IndiaPukyong Natl Univ, New Senior Oriented Smart Hlth Care Educ Ctr, Busan 48513, South Korea
Mishra, Prabhash
Lee, Byeong-Il
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机构:
Pukyong Natl Univ, Ind Convergence Bion Engn 4 0, Busan 48513, South Korea
Pukyong Natl Univ, Inst Informat Technol & Convergence, Digital Healthcare Res Ctr, Busan 48513, South Korea
Pukyong Natl Univ, Coll Informat Technol & Convergence, Div Smart Healthcare, Busan 48513, South KoreaPukyong Natl Univ, New Senior Oriented Smart Hlth Care Educ Ctr, Busan 48513, South Korea