NONIDEAL BEHAVIOR IN LIQUID METAL SOLUTIONS. PART 2 - CHEMICAL-PHYSICAL THEORY MODEL.

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作者
Stolcos, Thomas [1 ]
Eckert, Charles A. [1 ]
机构
[1] Univ of Illinois, Dep of Chemical, Engineering, Urbana, IL, USA, Univ of Illinois, Dep of Chemical Engineering, Urbana, IL, USA
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ELECTRONS; -; STEEL; Deoxidants;
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摘要
The 'physical' model developed previously is coupled with a 'chemical' model to account for the strong negative deviations from Raoult's law in systems forming intermetallic compounds. The resulting chemical-physical model represents well both Gibbs energies and enthalpies of highly solvated metal systems. New data are presented for two titanium systems, for which only a limited composition range is experimentally accessible. The theory permits facile extension of such limited data.
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页码:147 / 152
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