An experimental study of isotope effects on NMR parameters in the solid state

被引:0
|
作者
Stringfellow, Thomas C. [1 ,2 ]
Wu, Gang [1 ,3 ]
Wasylishen, Roderick E. [1 ]
机构
[1] Department of Chemistry, Dalhousie UniVersity, Halifax,NS,B3H 4J3, Canada
[2] Department of Chemistry, University of Wisconsin, Madison,WI,53706, United States
[3] Department of Chemistry, Queen’s University, Kingston,ON,K7L 3N6, Canada
来源
| 1997年 / 101卷 / 46期
关键词
Nuclear magnetic resonance spectroscopy - Solid state physics;
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摘要
We report on a variety of systems for which it has been possible to measure intrinsic isotope effects on the chemical shielding (the isotope shift) in the solid state. The spin systems investigated are11B(2/1H),13C(2/1H),15N(2/1H),31P(2/1H),95Mo(13/12C), and199Hg(13/12C). The results agree well with data available from solution NMR studies. © 1997 American Chemical Society.
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页码:9651 / 9656
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