Heterobimetallic dibridged complexes [Cp2Ta(μ-CO)(μ-PMe2)M'(CO)4] (M'=Cr, W): Synthesis and reactivity toward two-electron donor ligands L (L=PR3, Me2P(CH2)nPMe2, CNR)

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Boni, Gilles

Sauvageot, Philippe

Marpeaux, Emmanuel

Moise, Claude

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Organometallics | 1995年 / 14卷 / 12期

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[1] Reactivity of bimetallic dibridged complexes Cp2Ta(H)(μ-H)(μ-PMe2)M′(CO)4 (M′ = Cr, Mo, W) toward two-electron donor ligands L (L = PR3, Me2P(CH2)nPMe2).: Synthesis of linear trinuclear chain complexes Cp2Ta(H)2(μ-PMe2)M′(CO)4(Me2P(CH2)2PMe2)Cr(CO)5 (M′ = Mo, W)
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[2] HETEROBIMETALLIC DIBRIDGED COMPLEXES [CP(2)TA(MU-CO)(MU-PME(2))M'(CO)(4)] (M'=CR,W) - SYNTHESIS AND REACTIVITY TOWARD 2-ELECTRON DONOR LIGANDS L (L=PR(3), ME(2)P(CH2)(N)PME(2), CNR)
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[3] PREPARATION AND SPECTROSCOPICAL INVESTIGATIONS OF M(CO)4L2 AND M(CO)3L3 COMPLEXES (M = CR, MO, W, L=ME3SIOCH2PME2, ME2(CH2=CH)SIOCH2PME2)
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[4] ALTERNATIVE LIGANDS .26. M(CO)4L-COMPLEXES (M = CR, MO, W) OF THE CHELATING LIGANDS ME2ESIME2(CH2)2E'ME2(ME = CH3 E = P, AS E' = N, P, AS)
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[5] VIBRATIONAL V(CO) SPECTRA OF SPECIES M(CO)4L2 [M=CR,MO, OR W - L=PR3 OR P(OR)3]
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[6] Synthesis and spectroscopic properties of some new bi-, tri- and tetrametallic complexes of the type [M(CO)5L], [M(CO)4L2] and [M(CO)3L3] (M = Cr, Mo, W; L = [WI2(CO){Ph2P(CH2)2PPh(CH2)2PPh$ -2$/-P, P'}(eta2-RC2R')] (R = R' = Me, Ph; R = Me, R'= Ph)
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[7] Synthesis and spectroscopic properties of some new bi-, tri- and tetrametallic complexes of the type [M(CO)(5)L], [M(CO)(4)L-2] and [M(CO)(3)L-3] {M=Cr, Mo, W; L=[(WI2(CO){Ph2P(CH2)(2)P)over-bar-Ph(CH2)(2)PPh2-P,P'}(eta(2)-RC2R')] (R=R'=Me, Ph; R=Me, R'=Ph)}
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[9] TUNGSTEN COMPLEXES WITH STRONG PI-DONOR AND PI-ACCEPTOR LIGANDS - W(E)CL2(L)(PR3)2 (E=O, NR, S, AND L=CO, CNR, CH2=CHR AND O=CHME)
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[10] ALTERNATIVE LIGANDS .20. NOVEL COMPLEXES M(CO)3L WITH TRIPOD LIGANDS MEGE(OCH2PME2)3 AND MESI(OCH2PME2)X(CH2CH2PME2)3-X (M = CR, MO, W X = 0-2)
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