Determination of the concentration of active centres and the propagation reaction rate constants of the macrochain on polymerization of ethylene on highly active catalysts

被引：0
|
作者：
Zlotnikov, L.M. [1 ]
Ponomareva, Ye.L. [1 ]
Khaikin, S.Ya. [1 ]
Korotkov, S.I. [1 ]
Grigore'ev, V.A. [1 ]
Budtov, V.P. [1 ]
Ivanchev, S.S. [1 ]
机构：
[1] Okhtinsk 'Plastopolimer' Science, Production Assoc
来源：
Polymer science USSR | 1988年 / 30卷 / 01期
关键词：
D O I：
10.1016/0032-3950(88)90248-1
中图分类号：
学科分类号：
摘要：
14
引用
收藏
页码：16 / 22
相关论文
共 50 条
  • [21] Particle growth in emulsion polymerization - Determination of propagation rate constants and monomer concentration.
    vanHerk, AM
    POLYMERIC DISPERSIONS: PRINCIPLES AND APPLICATIONS, 1997, 335 : 17 - 30
  • [22] DETERMINATION OF NUMBER OF ACTIVE-CENTERS AND RATE CONSTANT OF PROPAGATION FOR PROPYLENE POLYMERIZATION WITH ZIEGLER-NATTA CATALYSTS
    ZAKHAROV, VA
    BUKATOV, GD
    CHUMAEVSKII, NB
    YERMAKOV, YI
    REACTION KINETICS AND CATALYSIS LETTERS, 1974, 1 (02): : 247 - 252
  • [23] DETERMINATION OF ACTIVE-SITES CONCENTRATION AND RATE CONSTANTS OF ELEMENTARY ACTS IN ETHYLENE POLYMERIZATION BY DEPOSITED CATALYSTS BASED ON TICL4 AND AL(C2H5)3
    BAULIN, AA
    SOKOLOV, VN
    SEMENOVA, AS
    CHIRKOV, NM
    SHALAEVA, LF
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1975, 17 (01): : 46 - 53
  • [24] Ethylene polymerization, and the copolymerizations of ethylene with hexene or norbornene with highly active mono(β-enaminoketonato) vanadium(III) catalysts
    Tang, Li-Ming
    Wu, Ji-Qian
    Duan, Yi-Qun
    Pan, Li
    Li, Yan-Guo
    Li, Yue-Sheng
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (06) : 2038 - 2048
  • [25] HIGHLY ACTIVE CATALYSTS FOR ETHYLENE POLYMERIZATION BY REDUCTION OF TICL4 WITH ORGANOMAGNESIUM COMPOUNDS
    HAWARD, RN
    ROPER, AN
    FLETCHER, KL
    POLYMER, 1973, 14 (08) : 365 - 372
  • [26] Highly active metallocene catalysts for olefin polymerization
    Kaminsky, W
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (09): : 1413 - 1418
  • [27] Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry
    di Lena, F
    Quintanilla, E
    Chen, P
    CHEMICAL COMMUNICATIONS, 2005, (46) : 5757 - 5759
  • [28] Bis(pyrazolyl) pyridine vanadium(III) complexes as highly active ethylene polymerization catalysts
    Abbo, Hanna S.
    Mapolie, Selwyn F.
    Darkwa, James
    Titinchi, Salam J. J.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (24) : 5327 - 5330
  • [29] NUMBER OF ACTIVE-CENTERS AND PROPAGATION RATE CONSTANTS IN THE PROPENE POLYMERIZATION ON SUPPORTED TI-MG CATALYSTS IN THE PRESENCE OF HYDROGEN
    BUKATOV, GD
    GONCHAROV, VS
    ZAKHAROV, VA
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1995, 196 (05) : 1751 - 1759
  • [30] Mechanism of olefin polymerization on supported Ziegler-Natta catalysts based on data on the number of active centers and propagation rate constants
    G. D. Bukatov
    V. A. Zakharov
    A. A. Barabanov
    Kinetics and Catalysis, 2005, 46 : 166 - 176
12345