Friedel-Crafts reaction of toluene with oxalyl chloride

被引：0
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作者：
Sakaino, Y. [1 ]
Sugawara, K. [1 ]
Terao, Y. [1 ]
Fujiwara, T. [1 ]
Mori, Y. [1 ]
Maeda, K. [1 ]
机构：
[1] Gunma Univ, Maebashi, Japan
来源：
Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals | 1996年 / 276-277卷 / pt 1-2期
关键词：
Addition reactions - Decomposition - Derivatives - Fluorescence - Fluorine compounds - Friedel-Crafts reaction - Mixing - Naphthalene - Phosphorescence - Solid state physics - Solutions - Structure (composition);
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摘要：
By the Friedel-Crafts reaction of toluene with oxalyl chloride, three kinds of fluorene derivatives (c, d, e), naphthalene derivative f, fluorenone derivative g, were obtained in addition to 4,4′-dimethyl benzophenone b.. In the compounds (c, d, e, f, g), c shows thermochromism above 135°C in solution, while e emits phosphorescence and f exhibits fluorescence at room temperature in the solid states.
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页码：271 / 275
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