Synthesis and characterisation of Poly(ethylene oxide)-block-Poly(para-phenylene vinylene)

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Lab de Recherche sur les Materiaux, Polymeres CNRS-UPPA, France [1 ]
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Synth Met | / 1 -3 pt 2卷 / 916-917期
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Fluorimetry - Polyparaphenylene vinylene - Schlenk technique;
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摘要
End-capped Poly(ethylene oxide)s have been synthesized starting from PEO and two different PPV monomers. The modification reactions lead to Poly(ethylene oxide)-block-Poly(para-phenylene vinylene) precursor copolymers which can be converted, in the reaction medium, to the di-block copolymers with a conjugated chain. The latter were characterised by Fluorimetry and Size Exclusion Chromatography.
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