MACROMOLECULAR STRUCTURE OF COALS. 6. MASS SPECTROSCOPIC ANALYSIS OF COAL-DERIVED LIQUIDS.

被引：0
|
作者：
Hooker II, Donald T. [1 ]
Lucht, Lucy M. [1 ]
Peppas, Nikolaos A. [1 ]
机构：
[1] Purdue Univ, Sch of Chemical, Engineering, West Lafayette, IN, USA, Purdue Univ, Sch of Chemical Engineering, West Lafayette, IN, USA
来源：
Industrial & Engineering Chemistry, Fundamentals | 1986年 / 25卷 / 01期
关键词：
COAL BYPRODUCTS - Spectroscopic Analysis - ORGANIC COMPOUNDS - Spectroscopic Analysis;
D O I：
暂无
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学科分类号：
摘要：
The macromolecular structure of coal networks was analyzed by depolymerizing coal samples using the Sternberg reductive alkylation and the Miyake alkylation techniques. Electron impact mass spectra showed peaks of greater abundance at 125-132, 252-260, 383-391, and 511-520 m/z ratios. Based on analysis of the patterns of the spectra, the cluster size of the cross-linked structure of bituminous coals was determined as 126-130. Various chemical species were identified.
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页码：103 / 108
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