Sulphur removal during coal pyrolysis in a fluidized bed of reducing condition

被引:0
|
作者
Liu, Qing [1 ]
Lu, Jun-Fu [1 ]
Zhang, Jian-Sheng [1 ]
Yue, Guang-Xi [1 ]
Lu, Ji-Ling [1 ]
机构
[1] Dept. of Thermal Eng., Tsinghua Univ., Beijing 100084, China
关键词
Desulfurization - Fluidized beds - Oxidation - Pyrolysis - Reduction;
D O I
暂无
中图分类号
学科分类号
摘要
There is a reducing area at the bottom of circulating fluidized bed furnace and the mechanism of desulfurrization in this area is different from that in the oxidation area. Four kinds of coal with different sulfur contents were pyrolyzed in fluidized bed in three reducing conditions. The results indicate that the sulfur in coal is mainly transformed to gaseous H2S. The generation speed of H2S increases with the increase of reducing degree. Due to oxygen in coal, some of the sulfur is transformed to SO2. Decomposition of sulphate is the main way of generating SO2. The rule of forming H2S and the effects of deoxidization and sulfur content on H2S were described.
引用
收藏
页码:367 / 370
相关论文
共 50 条
  • [1] Volatility of fluorine in coal during fluidized-bed pyrolysis
    Lu, Hai-Liang
    Chen, Hao-Kan
    Li, Wen
    Li, Bao-Qing
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2002, 30 (06):
  • [2] Transformation of arsenic in Yima coal during fluidized-bed pyrolysis
    Lu, HL
    Chen, HK
    Li, W
    Li, BQ
    FUEL, 2004, 83 (06) : 645 - 650
  • [3] Transformation of arsenic in Yima coal during fluidized-bed pyrolysis.
    Lu, HL
    Chen, HK
    Li, W
    Li, BQ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U869 - U869
  • [4] Coal pyrolysis and gasification in a fluidized bed thermogravimetric analyzer
    Samih, Said
    Chaouki, Jamal
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2018, 96 (10): : 2144 - 2154
  • [5] Effect of calcium oxide on pyrolysis of coal in a fluidized bed
    Zhu, TY
    Zhang, SY
    Hung, JJ
    Wang, Y
    FUEL PROCESSING TECHNOLOGY, 2000, 64 (1-3) : 271 - 284
  • [6] LOW TEMPERATURE REACTIONS IN FLUIDIZED BED COAL PYROLYSIS
    BASDEN, KS
    FUEL, 1960, 39 (04) : 359 - 360
  • [7] DESTRUCTION OF TAR DURING OXIDATIVE AND NONOXIDATIVE PYROLYSIS OF BITUMINOUS COAL IN A FLUIDIZED-BED
    VURAL, H
    WALSH, PM
    SAROFIM, AF
    BEER, JM
    COMBUSTION SCIENCE AND TECHNOLOGY, 1989, 63 (4-6) : 229 - 246
  • [8] Experiment of H2S Evolution during Coal Pyrolysis in Fluidized Bed
    Qin Hong
    Wang Qing
    Wang Qinhui
    Luo Zhongyang
    2010 ASIA-PACIFIC POWER AND ENERGY ENGINEERING CONFERENCE (APPEEC), 2010,
  • [9] Tar Emission during Pyrolysis of Low Rank Coal in a Circulating Fluidized Bed Reactor
    Kawabata, Yasumasa
    Nakagome, Hideki
    Wajirna, Takaaki
    Hosokai, Sou
    Sato, Hiroaki
    Matsuoka, Koichi
    ENERGY & FUELS, 2018, 32 (02) : 1387 - 1394
  • [10] MODELING OF STAGED FLUIDIZED-BED COAL PYROLYSIS REACTORS
    KAYIHAN, F
    REKLAITIS, GV
    INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1980, 19 (01): : 15 - 23