Design and synthesis of poly (aryl ether sulphone)s containing biphenyl moieties

被引：0
|
作者：
Ben, Teng [1 ]
Ruan, Ruxiang [1 ]
Yang, Zhe [1 ]
Chen, Chunhai [1 ]
Zhou, Hongwei [1 ]
Huang, Jiahui [1 ]
Zheng, Yubin [1 ]
Jiang, Zhenhua [1 ]
Wei, Zhanhai [1 ]
Wu, Zhongwen [1 ]
机构：
[1] Department of Chemistry, Jilin University, Changchun, 130023, China
来源：
American Chemical Society, Polymer Preprints, Division of Polymer Chemistry | 1999年 / 40卷 / 02期
关键词：
Crosslinking - Differential scanning calorimetry - Glass transition - Nuclear magnetic resonance spectroscopy - Synthesis (chemical) - X ray spectroscopy;
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学科分类号：
摘要：
Percentage of rigid chain length (PRCL) is the main factor to determine glass transition (Tg) of poly(aryl ether sulphone)s which have no side-group. Because biphenyl can increase the PRCL of such polymers, a series of poly(aryl ether sulphone)s containing biphenyl moieties and side-group, are designed and synthesized. All the polymers are detected by differential scanning calorimetry (DSC). Results showed that it is not only PRCL but also side-group has great effect on Tg. An empirical formula, Tg(°C) = 9.3PRCL-530.6, about the relationship between PRCL and Tg is deduced.
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页码：866 / 867
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