NEW TERNARY AND QUATERNARY TRANSITION-METAL SELENIDES: SYNTHESES AND CHARACTERIZATION.

被引：0

作者：

Keszler, Douglas A. ^{[1
]}

Ibers, James A. ^{[1
]}

Shang Maoyu ^{[1
]}

Lu Jiaxi ^{[1
]}

机构：

[1] Northwestern Univ, Dep of Chemistry,, Evanston, IL, USA, Northwestern Univ, Dep of Chemistry, Evanston, IL, USA

来源：

Journal of Solid State Chemistry | 1984年 / 57卷 / 01期

基金：

美国国家科学基金会;

关键词：

COBALT COMPOUNDS - CRYSTALS - Structure - NIOBIUM COMPOUNDS - TANTALUM COMPOUNDS;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

New ternary and quaternary transition-metal selenides have resulted from substitutional chemistry of the phase Nb//2Pd//3Se//8 and examination of the system Nb/Pd/Se. The structures of the phases Ta//2Pd//3Se//8, Co//2Ta//4PdSe//1//2, and Nb//2Pd//0//. //7//1Se//5 have been established through single-crystal X-ray methods. The compound Ta//2Pd//3Se//8 forms in space group Pbam with two formula units in a cell of dimensions a equals 15. 152(2), b equals 10. 631(2), and c equals 3. 540(1) A. This material is isostructural with Nb//2Pd//3Se//8. The compound Co//2Ta//4PdSe//1//2 forms in space group C2/m with two formula units in a cell of dimensions a equals 12. 951(3), b equals 3. 413(1), c equals 19. 277(5)A, and beta equals 110. 37(2) degree .

引用

页码：68 / 81

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