NOVEL pi -STRUCTURES VIA ELECTRON TRANSFER PROCESSES - FROM SPECTROSCOPY TO SYNTHESIS.

被引：0
|
作者：
Muellen, Klaus [1 ]
机构：
[1] Univ of Mainz, Mainz, West Ger, Univ of Mainz, Mainz, West Ger
来源：
Pure and Applied Chemistry | 1985年 / 58卷 / 01期
关键词：
HYDROCARBONS - OLIGOMERS - ORGANIC COMPOUNDS - Synthesis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Electron transfer reactions of unsaturated hydrocarbons can afford stable structures which appear extremely unfavorable on electrostatic grounds. The spectroscopic studies of the ionic pi -systems, in particular of the prevailing pi -charge distributions, suggest synthetic applications which are remote for the corresponding neutral compounds. Representative examples of reductive alkylations and of reductive sigma -bond formations (cleavages) are discussed.
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页码：177 / 186
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