Metal complexes of biologically important ligands, CXL [1]. Halfsandwich complexes of ruthenium(II), rhodium(III), iridium(III) and palladium(II), platinum(II) complexes with N,O-chelates of fluorine and thiophene containing α-amino acids

被引：0
|
作者：
Koch, Daniela [1 ]
Beck, Wolfgang [1 ]
机构：
[1] Dept. Chem. Ludwig-Maximilians-Univ., Butenandtstr. 5-13, D-81377 Munchen, Germany
来源：
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences | 2001年 / 56卷 / 12期
关键词：
Iridium compounds - Metal complexes - Ruthenium compounds - Palladium compounds - Rhodium compounds;
D O I：
10.1515/znb-2001-1204
中图分类号：
学科分类号：
摘要：
o-Fluorophenyl glycine and alanine, 2-thienyl glycine and alanine form with dinuclear, chloro bridged metal complexes the chiral N,0-chelates (arene)M(Cl)(NH2CHRCO2) (M = Ru, Rh, Ir; arene = cymene, Cp*) and (R3P)(Cl)M(NH2CHRCO2) (M = Pd, Pt) as mixtures of diastereoisomers or cis/trans-isomers, respectively.
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页码：1271 / 1280
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