One-Step Multifunctionalization of Random Copolymers via Self-Assembly

被引：0
|
作者：
Pollino, Joel M. [1 ]
Stubbs, Ludger P. [1 ]
Weck, Marcus [1 ]
机构：
[1] School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400, United States
来源：
Journal of the American Chemical Society | 2004年 / 126卷 / 02期
关键词：
Hydrogen bonds - Molecular structure - Palladium - Self assembly;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel methodology for random copolymer functionalization based on a noncovalent, one-step, multifunctionalization strategy has been developed. Random copolymers possessing both palladated-pincer complexes and diaminopyridine moieties (hydrogen-bonding entities) have been synthesized using ring-opening metathesis polymerization. Noncovalent functionalization of the resultant copolymers is accomplished via (1) directed self-assembly, (2) multistep self-assembly, and (3) one-step orthogonal self-assembly. This system shows complete specificity of each recognition motif for its complementary unit, with no observable changes in the association constants regardless of the degree of functionalization.
引用
收藏
页码：563 / 567
相关论文
共 50 条
  • [31] Self-assembly of interfacial and photoactive layers via one-step solution processing for efficient inverted organic solar cells
    Kang, Hongkyu
    Lee, Jinho
    Jung, Suhyun
    Yu, Kilho
    Kwon, Sooncheol
    Hong, Soonil
    Kee, Seyoung
    Lee, Seongyu
    Kim, Dongwon
    Lee, Kwanghee
    NANOSCALE, 2013, 5 (23) : 11587 - 11591
  • [32] A facile one-step synthesis of PTSA-doped tetraaniline nanostructure/magnetite nanoparticles via self-assembly method
    Basavaiah K.
    Pavankumar Y.
    Rao A.V.P.
    Journal of Nanostructure in Chemistry, 2013, 3 (1)
  • [33] Self-Sorted, Random, and Block Supramolecular Copolymers via Sequence Controlled, Multicomponent Self-Assembly
    Sarkar, Aritra
    Sasmal, Ranjan
    Empereur-mot, Charly
    Bochicchio, Davide
    Kompella, Srinath V. K.
    Sharma, Kamna
    Dhiman, Shikha
    Sundaram, Balasubramanian
    Agasti, Sarit S.
    Pavan, Giovanni M.
    George, Subi J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (16) : 7606 - 7617
  • [34] Multifunctionalization of synthetic polymer systems through self-assembly
    Gerhardt, W
    Crne, M
    Weck, M
    CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (24) : 6212 - 6221
  • [35] Supramolecular ABC Triblock Copolymers via One-Pot, Orthogonal Self-Assembly
    Yang, Si Kyung
    Ambade, Ashootosh V.
    Weck, Marcus
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (05) : 1637 - 1645
  • [36] Nanoscale self-assembly materials of amphiphilic random and block copolymers
    Terashima, Takaya
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [37] Polymerization-induced self-assembly of random bottlebrush copolymers
    Mei, Gaohuai
    Zheng, Yinan
    Fu, Yeran
    Huo, Meng
    POLYMER CHEMISTRY, 2022, 13 (37) : 5389 - 5396
  • [38] Self-assembly of amphiphilic ABA random triblock copolymers in water
    Kozawa, Susan K.
    Matsumoto, Kazuma
    Suzuki, Ayaka
    Sawamoto, Mitsuo
    Terashima, Takaya
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2019, 57 (03) : 313 - 321
  • [39] Spontaneous Self-Assembly and Micellization of Random Copolymers in Organic Solvents
    Sadeghi, Ilin
    Asatekin, Ayse
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2017, 218 (20)
  • [40] Synthesis of size controlled, functional hollow nanoparticles via photopolymerization and self-assembly of random copolymers
    Honglawan, Apiradee
    Yang, Shu
    Karunakaran, Raghuraman G.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
12345