Synthesis and cation-mediated electron transfer in intramolecular fluorescence quenching of donor-acceptor podands: Observation of Marcus inverted region in forward electron transfer reactions

被引：0

作者：

Jiang, Hua ^{[1
]}

Xu, Huijun ^{[1
]}

Ye, Jianping ^{[1
]}

机构：

[1] Institute of Photographic Chemistry, Bei-Sha-Tan, Beijing 100101, China

来源：

Journal of the Chemical Society. Perkin Transactions 2 | 2000年 / 05期

关键词：

Binding energy - Electrons - Fluorescence - Mass spectrometry - Nuclear magnetic resonance spectroscopy - Positive ions - Potassium - Quenching - Rate constants - Synthesis (chemical);

D O I：

10.1039/b000541j

中图分类号：

学科分类号：

摘要：

The synthesis of a series of donor-acceptor podands is described. The dependence of the rate constants of intramolecular photoinduced electron transfer on the exothermicity of the reaction was studied by stationary and time-resolved fluorescence spectroscopy. 1H NMR and computational studies suggest that the conformational change of the podands is restricted by K+ binding. As a result, the occurrence of highly exothermic photoinduced electron transfer reaction within the Marcus inverted region was observed.

引用

页码：925 / 930

共 50 条

[41] REABSORPTION EFFECT OF CHARGE-TRANSFER FLUORESCENCE BY EXCITED ELECTRON DONOR-ACCEPTOR COMPLEX
MASUHARA, H
MATAGA, N
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1972, 45 (01) : 43 - +
[42] Synthesis, spectral behaviour and photophysics of donor-acceptor kind of chalcones: Excited state intramolecular charge transfer and fluorescence quenching studies
Pannipara, Mehboobali
Asiri, Abdullah M.
Alamry, Khalid A.
Arshad, Muhammad N.
El-Daly, Samy A.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 136 : 1893 - 1902
[43] ELECTRON-TRANSFER REACTIONS IN THE MARCUS INVERTED REGION - CHARGE RECOMBINATION VERSUS CHARGE SHIFT REACTIONS
GOULD, IR
MOSER, JE
ARMITAGE, B
FARID, S
GOODMAN, JL
HERMAN, MS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) : 1917 - 1919
[44] Intramolecular electron transfer in porphyrin-anthraquinone donor-acceptor systems with varying molecular bridges
Duvva, Naresh
Ramya, A. R.
Reddy, Govind
Giribabu, L.
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2019, 23 (06) : 628 - 638
[45] Coordination control of intramolecular electron transfer in boronate ester-bridged donor-acceptor molecules
Shiratori, H
Ohno, T
Nozaki, K
Yamazaki, I
Nishimura, Y
Osuka, A
CHEMICAL COMMUNICATIONS, 1998, (15) : 1539 - 1540
[46] Ultrafast electron transfer reactions in donor-acceptor arrays as routes to a molecular switch.
Wasielewski, MR
Marsh, EM
Debreczeny, MP
Gosztola, D
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U225 - U225
[47] THE INFLUENCE OF THE SURROUNDING MEDIUM ON ELECTRON-TRANSFER REACTIONS IN LINKED DONOR-ACCEPTOR MOLECULES
ARCHER, MD
GADZEKPO, VYP
BOLTON, JR
CROATICA CHEMICA ACTA, 1987, 60 (03) : 577 - 580
[48] Photo-induced intramolecular electron transfer in phenoxazine-phthalocyanine donor-acceptor systems
Srivishnu, K. S.
Naresh, Madarapu
Rao, J. Laxmikanth
Giribabu, Lingamallu
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2022, 26 (03) : 253 - 262
[49] EFFECT OF EXTERNAL-PRESSURE ON PHOTOINDUCED ELECTRON-TRANSFER REACTIONS IN THE MARCUS INVERTED REGION
CHUNG, WS
TURRO, NJ
GOULD, IR
FARID, S
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20): : 7752 - 7757
[50] A unified description of superexchange and sequential donor-acceptor electron transfer mediated by a molecular bridge
Petrov, EG
May, V
JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (45): : 10176 - 10186

← 1 2 3 4 5 →