Mechanism and Selectivity of the Hydrogenation of Alkadienes to Alkenes in the Presence of Group VIII Metals.

被引：0
|
作者：
Kripylo, Peter
Strecha, Herwig
Mueller, Gerhard
机构：
来源：
Chemische Technik (Leipzig) | 1980年 / 32卷 / 10期
关键词：
CATALYSTS - Metals of VIII Group - CHEMICAL REACTIONS - NICKEL AND ALLOYS - ORGANIC COMPOUNDS - Chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Similarly to platinum catalysts, also rhodium, iridium and nickel catalyst exhibit low selectivity in the hydrogenation of conjugated alkadienes. Data area presented which show that this low selectivity is caused by the fact that these catalysts have no ability to stabilize pi -allyl adsorbed intermediates. Only palladium and cobalt catalysts demonstrate this ability and that is why that show excellent selectivity in the conversion of alkadiene to respective alkenes by hydrogenation.
引用
收藏
页码：531 / 532
相关论文
共 50 条
  • [21] Mechanism of nitrile hydrogenation to amines over supported transition metals.
    Sachtler, WMH
    Huang, YY
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U914 - U915
  • [22] INFLUENCE OF NATURE OF SOLVENT AND REACTION MEDIUM ON KINETICS AND MECHANISM OF HYDROGENATION OF CERTAIN AROMATIC COMPOUNDS ON GROUP VIII METALS. VII. HYDROGENATION OF BENZYLIDENEACETONES ON PALLADIUM AND NITROBENZENES ON SKELETAL NICKEL.
    Finkel'shtein, A.V.
    Morozova, M.I.
    Kuz'mina, Z.M.
    Tarbeeva, N.A.
    Kinetics and Catalysis, 1987, 28 (1 pt 2) : 188 - 190
  • [23] Catalytic activity of the VIII Group metals in the hydrogenation and isomerization of α- and β-pinenes
    I. V. Deliy
    I. L. Simakova
    Russian Chemical Bulletin, 2008, 57 : 2056 - 2064
  • [24] ANILINE HYDROGENATION PRESSURIZED BY SOME GROUP-VIII METALS
    SOKOLSKII, DV
    UALIKHANOVA, A
    TEMIRBULATOVA, AE
    ZHURNAL ORGANICHESKOI KHIMII, 1982, 18 (10): : 2078 - 2081
  • [25] Catalytic activity of the VIII Group metals in the hydrogenation and isomerization of α- and β-pinenes
    Deliy, I. V.
    Simakova, I. L.
    RUSSIAN CHEMICAL BULLETIN, 2008, 57 (10) : 2056 - 2064
  • [26] Catalytic Hydrogenation of Pentanoic Acid over VIII Group Metals
    Simakova, Irina L.
    Demidova, Yuliya S.
    Prikhodko, Sergey A.
    Simonov, Mikhail N.
    Shabalin, Anton Yu
    JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY, 2015, 8 (03): : 439 - 449
  • [27] INFLUENCE OF THE NATURE OF SOLVENT AND REACTION MEDIUM ON KINETICS AND MECHANISM OF HYDROGENATION OF CERTAIN AROMATIC COMPOUNDS ON GROUP VIII METALS. VI. FLUCTUATIONS OF STATIONARY POTENTIAL OF THE CATALYST DURING HYDROGENATION OF NITROBENZENES.
    Finkelshtein, A.V.
    Anisimov, L.N.
    Kinetics and Catalysis, 1987, 28 (1 pt 2) : 185 - 187
  • [28] MECHANISM OF ACTIVATED SINTERING OF VI GROUP REFRACTORY METALS.
    Panin, V.E.
    Kochepasov, I.I.
    Science of Sintering, 1979, 11 (01): : 33 - 41
  • [29] PHOTOCATALYTIC DECOMPOSITION OF HYDROGEN SULFIDE IN THE PRESENCE OF POLYMER IMMOBILIZED CADMIUM SULFIDE. PROMOTION BY I AND VIII GROUP METALS.
    Gruzdkov, Yu.A.
    Savinov, E.N.
    Parmon, V.N.
    1600, (12):
  • [30] SELECTIVITY OF GROUP 8 METALS FOR CATALYTIC HYDROGENATION AND HYDROGENOLYSIS OF PHENOL
    YAMAMOTO, H
    KWAN, T
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1969, 17 (06) : 1081 - +
12345