Initiating systems for suspension polymerization of vinyl chloride

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Russ. J. Appl. Chem. | / 8卷 / 1308-1312期
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Chlorine compounds - Oxidation - Polymerization - Potassium compounds - Reducing agents - Suspensions (components) - Suspensions (fluids);
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The effect of initiating systems based on di-2-ethylhexyloxycarbonyl peroxide on the duration of suspension polymerization of vinyl chloride is studied. The feasibility is demonstrated of accelerating the synthesis by using appropriate nitrogen-containing reducing agents and a water-soluble coinitiator. A mechanism is proposed for acceleration of polymerization in the presence of the initiating system di-2-ethylhexyloxycarbonyl peroxide-potassium persulfate. © 1997 MAHK Hayka/Interperiodica Publishing.
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