Salting-out and diluent effects in extraction process of oxalic acid by trialkyl phophin oxide

被引:0
|
作者
Zhang, Ping [1 ]
Cai, Shuihong [1 ]
Zhang, Qiuhua [1 ]
机构
[1] East China Univ of Science and, Technology, Shanghai, China
关键词
Leaching;
D O I
暂无
中图分类号
O6 [化学]; TQ03 [化学反应过程]; TQ02 [化工过程(物理过程及物理化学过程)];
学科分类号
0703 ; 081701 ; 081704 ;
摘要
It is discovered that under the same conditions the distribution coefficient of oxalic acid D decrease with different diluents in the order of aromatic hydrocarbon, alkane, halogenated hydrocarbon. This order is independent of the concentration of extractant in the organic phase. For the salting-out agents used in extraction of oxalic acid, the effect has the following order: MgCl2>NaCl>KCl. D decreases and then increases with increasing concentration of salting-out agents in the aqueous phase, and the minimum D appears at 0.5-1.0 mol/L.
引用
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页码:312 / 316
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