Metal-support interaction in Na-W-Mn/SiO2 catalyst

被引:0
|
作者
Chen, H.-S.
Niu, J.-Z.
Zhang, B.
Li, S.-B.
机构
关键词
D O I
暂无
中图分类号
学科分类号
摘要
The interaction of metal components with silica support in Na-W-Mn/SiO2 was studied. The inducing effect of sodium makes amorphous silica transferred to α-cristobalite during calcination, and the specific surface area decreases enormously as a consequence. When sodium alone is loaded, the silica has almost no micropores retained after calcination. When tungsten is loaded together with sodium, quite regular pores at the size of micron can be formed in silica during the phase transition.
引用
下载
收藏
页码:814 / 816
相关论文
共 50 条
  • [41] Isovalent Substitutions in Composite Catalysts Na/W/Mn/SiO2
    Nipan, G. D.
    Loktev, A. S.
    Dedov, A. G.
    Moiseev, I. I.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (09) : 1115 - 1119
  • [42] The heat-promoted metal-support interaction of a PtCu/SiO2 carbon-free catalyst for the methanol oxidation and oxygen reduction reactions
    Zhao, Quanqing
    Zhi, Han
    Yang, Liu
    Xu, Feng
    RSC SUSTAINABILITY, 2023, 1 (08): : 1989 - 1994
  • [43] Catalytic Behavior of Different Amounts of WO4 Active Sites on Na-W-Mn/SiO2 Catalysts for Oxidative Coupling of Methane
    Song, Jiaxin
    Fan, Xiaoqiang
    Liu, Baijun
    Zhao, Zhen
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2024, 45 (09):
  • [44] INHIBITING EFFECT OF METAL-SUPPORT REACTION ON CARBONIZATION OF NI/SIO2 FILMS
    KEPINSKI, L
    CARBON, 1992, 30 (07) : 949 - 955
  • [45] Critical Surface Parameters for the Oxidative Coupling of Methane over the Mn-Na-W/SiO2 Catalyst
    Hayek, Naseem S.
    Lucas, Nishita S.
    Damouny, Christine Warwar
    Gazit, Oz M.
    ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (46) : 40404 - 40411
  • [46] Effect of thermal treatment on the stability of Na-Mn-W/SiO2 catalyst for the oxidative coupling of methane
    Matras, Dorota
    Vamvakeros, Antonios
    Jacques, Simon D. M.
    Grosjean, Nicolas
    Rollins, Benjamin
    Poulston, Stephen
    Stenning, Gavin B. G.
    Godini, Hamid R.
    Drnec, Jakub
    Cernik, Robert J.
    Beale, Andrew M.
    FARADAY DISCUSSIONS, 2021, 229 (00) : 176 - 196
  • [47] Boosting the selective hydrogenation of biphenyl to cyclohexylbenzene over bimetallic Ni-Ru/SiO2 catalyst via enhancing strong metal-support interaction
    Yang, Jingyi
    Gao, Yongzhen
    Fan, Jie
    Wang, Jieqiong
    Yang, Tao
    Bing, Zezheng
    Zhang, Meng
    Liu, Zhongyi
    APPLIED SURFACE SCIENCE, 2024, 660
  • [48] Metal-support interactions -: Part 1:: Physical interactions during Co/SiO2 catalyst preparations and treatments.
    Puskas, I
    Fleisch, TH
    Kaduk, JA
    Meyers, BL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U258 - U259
  • [49] Specific Phase Transformations of K/W/Mn/SiO2 Composite Catalyst
    Nipan, G. D.
    INORGANIC MATERIALS, 2018, 54 (01) : 96 - 101
  • [50] Oxidative coupling of methane over W-Mn/SiO2 catalyst
    Li, SB
    CHINESE JOURNAL OF CHEMISTRY, 2001, 19 (01) : 16 - 21