Study on solubility of solid solutes in a supercritical fluid with entrainers. (I) Chemical association model

被引:0
|
作者
Zhou, Qingrong [1 ]
Zhang, Zeting [1 ]
Zhu, Meiwen [1 ]
Yu, Enping [1 ]
机构
[1] Beijing Univ of Chemical Technology, Beijing, China
来源
Huagong Xuebao/Journal of Chemical Industry and Engineering (China) | 1995年 / 46卷 / 03期
关键词
Association reactions - Inclusions - Solid solutions - Supercritical fluid extraction;
D O I
暂无
中图分类号
学科分类号
摘要
Based on the theory of chemical association equilibria, a general model for calculating solubilities of solid solutes in a supercritical fluid (SCF) with entrainers was derived with of a equation. This model could be modified and simplified into semi-empirical correlations. The two models for predicting solubilities of solid solutes in a SCF with entrainers correlate the experimental data from literature and this work satisfactorily.
引用
收藏
页码:317 / 323
相关论文
共 50 条
  • [21] A new model for correlating the solubility of solids in supercritical CO2 and study on some systems (I):: The new model
    Zhong, MH
    Han, BX
    Ke, J
    Yan, HK
    Peng, DY
    CHINESE CHEMICAL LETTERS, 1998, 9 (02) : 145 - 148
  • [22] Measurement of solid solubility of warfarin in supercritical carbon dioxide and recrystallization study using supercritical antisolvent process
    Ciou, Jheng-Ming
    Wang, Bo-Cheng
    Su, Chie-Shaan
    Liu, Jun-Jen
    Sheu, Ming-Thau
    ADVANCED POWDER TECHNOLOGY, 2018, 29 (03) : 479 - 487
  • [23] Calculation of solubility of solid solutes in mixed non-aqueous solvents within the limits of the theory of molecular association
    Totchasov, E. D.
    Nikiforov, M. Yu.
    Al'per, G. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 48 (03) : 474 - 478
  • [24] Calculation of solubility of solid solutes in mixed non-aqueous solvents within the limits of the theory of molecular association
    E. D. Totchasov
    M. Yu. Nikiforov
    G. A. Al’per
    Journal of Structural Chemistry, 2007, 48 : 474 - 478
  • [25] RELATIONSHIP BETWEEN RETENTION OF A SOLID SOLUTE IN LIQUID AND SUPERCRITICAL FLUID CHROMATOGRAPHY AND ITS SOLUBILITY IN THE MOBILE PHASE
    BARTLE, KD
    CLIFFORD, AA
    JAFAR, SA
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (05): : 855 - 860
  • [26] Correlation of solid solubility for biological compounds in supercritical carbon dioxide: comparative study using solution model and other approaches
    Cheng, JS
    Tang, M
    Chen, YP
    FLUID PHASE EQUILIBRIA, 2002, 194 : 483 - 491
  • [27] SUPERCRITICAL PHASE-BEHAVIOR - DESCRIPTION OF THE SOLUBILITY OF BINARY SOLID MIXTURES IN A SUPERCRITICAL SOLVENT WITH A LATTICE GAS-MODEL
    BALBUENA, P
    CAMPANELLA, E
    GRIBAUDO, L
    FLUID PHASE EQUILIBRIA, 1991, 62 (03) : 225 - 238
  • [28] Interaction of pharmaceutical hydrates with supercritical CO2 -: Solubility, solid-state and chemical modifications
    Bettini, R
    Bertolini, G
    Frigo, E
    Rossi, A
    Casini, I
    Pasquali, I
    Giordano, F
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2004, 77 (02) : 625 - 638
  • [29] Calculation of solid solubility of complex molecules in supercritical carbon dioxide using a solution model approach
    Cheng, JS
    Tang, M
    Chen, YP
    MOLECULAR SIMULATION, 2003, 29 (12) : 749 - 754
  • [30] Novel density-based model for the correlation of solid drugs solubility in supercritical carbon dioxide
    Si-Moussa, Cherif
    Belghait, Aicha
    Khaouane, Latifa
    Hanini, Salah
    Halilali, Asmaa
    COMPTES RENDUS CHIMIE, 2017, 20 (05) : 559 - 572