Existence of doubly charged lead monohydrate: Experimental evidence and theoretical examination

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作者：
机构：
[1] Shi, Tujin
[2] Orlova, Galina
[3] Guo, Jingzhong
[4] Bohme, Diethard K.
[5] Hopkinson, Alan C.
[6] Siu, K. W. Michael
来源：
Siu, K.W.M. (kwmsiu@yorku.ca) | 1600年 / American Chemical Society卷 / 126期
关键词：
Activation analysis - Charge transfer - Molecular structure - Reaction kinetics;
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摘要：
Despite reports to the contrary, doubly charged lead monohydrate is a stable species against both proton and charge transfers. [Pb(H 2O)]2+ has been observed as a minor product in the ligand-exchange reaction of [Pb(CH3CN)]2+ with H 2O after collisional activation. Density functional theory has been used to examine reaction profiles of [Pb(H2O)n] 2+ where n = 1, 2, and 3.
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