The Reactivity of Addends in the Diene Synthesis Reaction

被引：5
|
作者：
Konovalov, A.I. [1 ]
机构：
[1] Ul’yanov-Lenin Kazan State University, Russia
来源：
Russian Chemical Reviews | 1983年 / 52卷 / 11期
关键词：
D O I：
10.1070/RC1983v052n11ABEH002916
中图分类号：
O62 [有机化学]; TQ [化学工业];
学科分类号：
070303 ; 0817 ; 081704 ;
摘要：
The principal electronic factors determining the reactivity of addends in the diene synthesis reaction are considered. The applicability of the model taking into account both the donor-acceptor properties of the reactants and their relative stabilities with respect to the reaction described by délocalisation energies or reaction enthalpies is demonstrated. The unusual influence of the donor-acceptor interactions between the addends on their selectivity in the Diels-Alder reaction is also demonstrated and the qualitative differences between the effects of the pair interactions of theantisymmetric and symmetrical frontier orbitals are noted. The bibliography includes 103 references. © 1983 Turpion Ltd. All rights reserved.
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页码：1064 / 1080
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