KINETICS OF THE 2 Al(1) plus AlCl3(g) equals 3AlCl(g) REACTION IN THE SUBHALIDE PROCESS OF ALUMINUM.

被引：0
|
作者：
Kikuchi, Takeaki
Kurosawa, Toshio
Yagihashi, Tetsuo
机构：
来源：
Transactions of the Japan Institute of Metals | 1972年 / 13卷 / 05期
关键词：
PHYSICAL CHEMISTRY;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The kinetics of the reaction was studied by the flow method under a reduced pressure of trichloride at 900 to 1100 degree C. On the basis of the results, reaction rate is expressed in an equation. The apparent activation energy of this reaction was 11. 8 kcal/mol. The reaction ratio of AlCl//3 increased with rising temperature and decreasing trichloride pressure. Aluminum was deposited mostly as small spherical particles in the high temperature zone and dendrites in the lower temperature zone.
引用
收藏
页码：355 / 358
相关论文
共 50 条
  • [31] Determination of aluminium in AlCl3 and Al2O3 modified silica catalyst supports
    M. Nieminen
    Lauri Niinistö
    Fresenius' Journal of Analytical Chemistry, 1999, 364 : 224 - 227
  • [32] Al2O3-CVD by an AlCl3/O2 Reactive Mixture.
    Altena, H.
    Lux, B.
    International Journal of Refractory Metals and Hard Materials, 1987, 6 (01) : 53 - 56
  • [33] Electrodeposition of Al, Mn, and Al–Mn Alloy on aluminum electrodes from molten salt (AlCl3–NaCl–KCl)
    M. Jafarian
    A. Maleki
    I. Danaee
    F. Gobal
    M. G. Mahjani
    Journal of Applied Electrochemistry, 2009, 39 : 1297 - 1303
  • [34] Synthesis of 1,2,3,4-Tetrahydroquinolines Using AlCl3 in Aqua Mediated
    Behbahani, Farahnaz K.
    Ziaei, Parisa
    JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE, 2014, 58 (01): : 44 - 48
  • [35] Mechanochemical synthesis of the α-AlH3/LiCl nano-composites by reaction of LiH and AlCl3: Kinetics modeling and reaction mechanism
    Duan Congwen
    Cao Yizheng
    Hu Lianxi
    Zhang Yuling
    Fu Dong
    Ma Jinlong
    Zhang Jinghong
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (42) : 23716 - 23725
  • [36] Mechanistic investigations of the disproportionation reaction catalyzed by AlCl3/NH2-MIL-53(Al) to produce dimethyldichlorosilane
    Wenyuan Xu
    Zhaohua Cheng
    Liubin Mo
    Haoting Si
    Mengsha Shen
    Jiaxi Peng
    Zhili Fang
    Mengyin Liao
    Xi Chen
    Silicon, 2024, 16 : 1795 - 1807
  • [37] EFFECTS OF WATER AND HYDROGEN-CHLORIDE ON THE REACTION OF 1,1-DIPHENYLETHYLENE WITH ALCL3
    MASURE, M
    SAUVET, G
    SIGWALT, P
    POLYMER BULLETIN, 1980, 2 (10) : 699 - 705
  • [38] Mechanistic investigations of the disproportionation reaction catalyzed by AlCl3/NH2-MIL-53(Al) to produce dimethyldichlorosilane
    Xu, Wenyuan
    Cheng, Zhaohua
    Mo, Liubin
    Si, Haoting
    Shen, Mengsha
    Peng, Jiaxi
    Fang, Zhili
    Liao, Mengyin
    Chen, Xi
    SILICON, 2024, 16 (04) : 1795 - 1807
  • [39] THE ROLE OF ALCL3 AND AL2CL6 IN THE CATALYZED DECOMPOSITION OF ORGANIC HALIDES
    JASIEN, PG
    JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (17): : 6502 - 6508
  • [40] Kinetics and hydrogen storage performance of Li-Mg-N-H systems doped with Al and AlCl3
    Gennari, Fabiana (gennari@cab.cnea.gov.ar), 1600, Elsevier Ltd (765):
12345