Mechanochemistry of sodium azide

被引:0
|
作者
Hara, Yasutake [1 ]
Oda, Makoto [1 ]
Nakamura, Hidetsugu [1 ]
机构
[1] Kyushu Inst of Technology, Kitakyushu, Japan
关键词
Chemistry - Crystal defects - Crystal lattices - Decomposition - Milling (machining) - Particle size analysis;
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摘要
The effects of milling on the crystallinity and the thermal reactivity of sodium azide were measured to evaluate their hazardous properties. Mean particle diameter markedly decreases and comes to milling equilibrium up to a milling time of 6 hours under this experimental condition. Particle diameter becomes smaller by milling on account of accumulation of mechanical energy and its decomposition temperature becomes lower resulting from the increase in lattice defects.
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页码:4 / 9
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