CHLORINATION OF METHANE BY BUBBLING THROUGH A MELT OF COPPER AND ZINC CHLORIDES.

被引：0
|
作者：
Skudaev, V.I. [1 ]
Solomonov, A.B. [1 ]
Gertsen, P.P. [1 ]
Cherenev, L.A. [1 ]
Rozanov, V.N. [1 ]
机构：
[1] Perm' Polytechnic Inst, USSR, Perm' Polytechnic Inst, USSR
来源：
Journal of applied chemistry of the USSR | 1986年 / 59卷 / 4 pt 2期
关键词：
CHEMICAL REACTIONS - Reaction Kinetics - COPPER COMPOUNDS - POTASSIUM COMPOUNDS - ZINC COMPOUNDS;
D O I：
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摘要：
In this work the authors studied chlorination of methane by a melt of copper and zinc chlorides, which approximates to an ideal solution. Experimental evidence shows that chlorination of methane by copper(II) chloride in a melt with zinc chloride under bubbling conditions conforms to a kinetic equation of order 0. 2 with respect to methane and 1. 7 with respect to copper(II) chloride. The activation energy of the process is 108 kJ/mole. The character of the dependence of the reaction rate on the zinc chloride concentration confirms the views advanced earlier with regard to a mechanism including a stage of thermal dissociation of copper(II) chloride.
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页码：773 / 777
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