CHLORINATION OF METHANE BY BUBBLING THROUGH A MELT OF COPPER AND ZINC CHLORIDES.

被引：0

作者：

Skudaev, V.I. ^{[1
]}

Solomonov, A.B. ^{[1
]}

Gertsen, P.P. ^{[1
]}

Cherenev, L.A. ^{[1
]}

Rozanov, V.N. ^{[1
]}

机构：

[1] Perm' Polytechnic Inst, USSR, Perm' Polytechnic Inst, USSR

来源：

Journal of applied chemistry of the USSR | 1986年 / 59卷 / 4 pt 2期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics - COPPER COMPOUNDS - POTASSIUM COMPOUNDS - ZINC COMPOUNDS;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

In this work the authors studied chlorination of methane by a melt of copper and zinc chlorides, which approximates to an ideal solution. Experimental evidence shows that chlorination of methane by copper(II) chloride in a melt with zinc chloride under bubbling conditions conforms to a kinetic equation of order 0. 2 with respect to methane and 1. 7 with respect to copper(II) chloride. The activation energy of the process is 108 kJ/mole. The character of the dependence of the reaction rate on the zinc chloride concentration confirms the views advanced earlier with regard to a mechanism including a stage of thermal dissociation of copper(II) chloride.

引用

页码：773 / 777

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