Phase compatibility and superconductivity of Y-Ba-Cu-O compounds

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作者
Wadayama, Yoshihide [1 ]
Kudo, Kotaro [1 ]
Nagata, Akihiko [1 ]
Ikeda, Keisuke [1 ]
Hanada, Shuji [1 ]
Izumi, Osamu [1 ]
机构
[1] Tohoku Univ, Japan
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Ceramic Materials - Oxides - Superconductivity;
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摘要
Superconducting properties of Y-Ba-Cu-O compounds were investigated in relation to precipitation of second phases. Contour lines of Jc, Tc and diamagnetic signal intensities were presented in the YO1.5-BaO-CuO system. These superconducting properties decreased steeply with BaCuO2 precipitation, and the maximum Jc was obtained in the yttrium-rich composition of Y1.2Ba2Cu3O7-y. It is considered, therefore, that the BaCuO2 precipitating around the YBa2Cu3O7-y grains interrupt the superconducting current pass at the grain boundary. Yttrium-rich composition, which inhibits BaCuO2 precipitation, is effective for the preparation of the high-Jc sample.
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