MONOMERIC N-HYDROXYETHYLATED AMIDES.

被引：0

作者：

Sonnet, Philip E. ^{[1
]}

Piotrowski, Edwin G. ^{[1
]}

Wise, William B. ^{[1
]}

Micich, Thomas J. ^{[1
]}

机构：

[1] USDA, Philadelphia, PA, USA, USDA, Philadelphia, PA, USA

来源：

JAOCS, Journal of the American Oil Chemists' Society | 1986年 / 63卷 / 12期

关键词：

CATALYSIS; -; DETERGENTS; Wetting;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Oxyethylated amides that are good wetting agents have been prepared as mixtures by allowing amides to react with ethylene oxide under base catalysis. Individual components of such mixtures can be synthesized by allowing 1-alkylaziridines to react with p-toluenesulfonic acid in monomethylethers of di-, tri- and tetraethylene glycol used as solvents. The aminoethers are then acylated, and the methylether group is removed with trimethylsilyliodide from the resulting amide ethers. The sequence should allow the synthesis of specific wetting agents of quite varied structure (alkyl, aryl groups) with an option for isotropic labeling for more detailed analysis of the wetting properties.

引用

页码：1579 / 1583

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