Mathematical Modelling of the Bulk Polymerization in Heterogeneous Systems.

被引：0
|
作者：
Bulle, H.
Meinhard, R.
Naumann, W.
机构：
来源：
Plaste und Kautschuk | 1973年 / 20卷 / 06期
关键词：
MATHEMATICAL MODELS - POLYVINYL CHLORIDE;
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学科分类号：
摘要：
The mathematical model of bulk polymerization for closed two-phase systems is formulated on the basis of a physico-chemical process analysis. It can be adapted to the conditions of precipitation and polymerization by means of the kinetic expressions f//M, f//I, f//1//P and f//2//P. It contains as a special case the process model developed by Crosato-Arnaldi and coworkers for the precipitation polymerization of vinyl chloride. From a study of the model parameters using estimated values results that the model properly reproduces qualitatively the output-time curve of the monomer during the pprecipitation polymerization.
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页码：406 / 409
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