trans-Diaquabis(nicotinamide-N1)bis(4-nitrobenzoato-O)cobalt(II)

被引:0
|
作者
Hokelek, Tuncer
Necefoglu, Hacali
机构
关键词
D O I
暂无
中图分类号
学科分类号
摘要
The title cobalt complex, [Co(C7H4NO4)2 (C6H6N2O)2(H2O)2], is monomeric and centrosymmetric, and contains two water molecules, two 4-nitrobenzoate and two nicotinamide (NA) ligands, all acting as monodentate ligands. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with a distorted octahedral coordination completed by the pyridine N atoms of the NA ligand, at a distance of 2.134 (2) angstroms. The water molecules are hydrogen bonded to the carboxyl O atoms [O···O 2.634 (5) angstroms].
引用
收藏
页码:1242 / 1244
相关论文
共 50 条
  • [21] Diaquabis(1H-imidazole-κN3)bis(4-nitrobenzoato-κO)cobalt(II)
    Xu, TG
    Xu, DJ
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M1131 - M1133
  • [22] Diaquabis(4-methoxybenzoato-κO 1)bis(nicotinamide-κN 1)cobalt(II) dihydrate
    Hokelek, Tuncer
    Dal, Hakan
    Tercan, Baris
    Tenlik, Erdinc
    Necefoglu, Hacali
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M910 - U480
  • [23] catena-poly[diaquabis(nicotinamide-N1)copper(II)-μ-sulfato-O:O′]
    Kozlevcar, B
    Leban, I
    Sieler, J
    Segedin, P
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 39 - 41
  • [24] trans-diaquabis(pyridine-4-carboxylato)cobalt(II) dihydrate
    Yan, ZQ
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : M116 - M117
  • [25] Redetermination of trans-diaquabis(picolinato-κ2N,O)cobalt(II) dihydrate
    Heren, Z
    Ersanli, CC
    Keser, C
    Iskeleli, NO
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M796 - M798
  • [26] Synthesis and crystal structure of trans-diaquabis (hexamethylenetetramine-N)bis(isothiocyanato)cobalt(II) trans-tetraaquabis(isothiocyanato)cobalt(II) dihydrate
    Liu, Q
    Xi, HT
    Sun, XQ
    Zhu, HF
    Yu, KB
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 21 (04) : 355 - 358
  • [27] Diaquabis(4-bromobenzoato-kO)-bis(nicotinamide-κN1)cobalt(II)
    Hoekelek, Tuncer
    Caylak, Nagihan
    Necefoglu, Hacali
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1873 - U810
  • [28] THE STRUCTURE OF TRANS-DIAQUABIS[(+/-)-HYDROGEN MALATO]COBALT(II) DIHYDRATE
    KARIPIDES, A
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (MAY): : 1115 - 1117
  • [29] trans-Diaquabis(5,5-diphenylhydantoinato-κN3)-bis(hexamethylenetetraamine-κN)cobalt(II) hemihydrate
    Hu, Xi-Lan
    Xu, Xing-You
    Liu, Hai-Feng
    Xu, Tong-Tao
    Wang, Da-Qi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2976 - M2977
  • [30] Bis(guanidinium) trans-diaquabis(malonato-k2O, O′) cobaltate(II)
    Najafpour, M. Mahdi
    Holynska, Malgorzata
    Lis, Tadeusz
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M186 - U1781