RAMAN SPECTRA OF RARE-EARTH PHOSPHATE GLASSES.

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作者
Morgan, Steven H. [1 ]
Magruder, Robert H. [1 ]
Silberman, Enrique [1 ]
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[1] Fisk Univ, Nashville, TN, USA, Fisk Univ, Nashville, TN, USA
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SPECTROSCOPY; RAMAN; -; Applications;
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Raman spectra have been recorded for glasses in the binary systems CeO//2-P//2O//5 and Pr//2O//3-P//2O//5. The cerium phosphate glasses were prepared having different concentrations of CeO//2 and the praseodymium phosphate glasses with different ratios of Pr**3** plus to Pr**4** plus . The spectra indicate that both cerium and praseodymium enter the glass in modifying sites. We see no changes in the Raman spectra with Pr**3** plus /Pr**4** plus ratio. Measurements of the density and glass transition temperature are also reported.
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