PHASE STABILITY OF CdF2-LiF-AlF3-PbF2 GLASSES.

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作者
El-Bayoumi, Osama H. [1 ]
Simmons, Catherine J. [1 ]
Clausen Jr., Edward M. [1 ]
Suscavage, Michael J. [1 ]
Simmons, Joseph H. [1 ]
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[1] Rome Air Development Cent, Hanscom, AFB, MA, USA, Rome Air Development Cent, Hanscom AFB, MA, USA
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GLASS MANUFACTURE - Physical Chemistry;
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The techniques of scanning electron microscopy, energy dispersive X-ray microanalysis, and dark-field transmission electron microscopy were combined to study the phase stability of CdF//2-LiF-AlF//2-PbF//2 glasses. The selected compositions, presumed to be exceptionally stable exhibited a liquid-liquid immiscibility phase transition; this led to the formation of two amorphous phases consisting of a matrix near the original glass composition and an isolated spherical phase which was richer in CdF//2 and poorer in PbF//2 than the matrix.
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页码:510 / 513
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