PHASE STABILITY OF CdF2-LiF-AlF3-PbF2 GLASSES.

被引：0
|
作者：
El-Bayoumi, Osama H. [1 ]
Simmons, Catherine J. [1 ]
Clausen Jr., Edward M. [1 ]
Suscavage, Michael J. [1 ]
Simmons, Joseph H. [1 ]
机构：
[1] Rome Air Development Cent, Hanscom, AFB, MA, USA, Rome Air Development Cent, Hanscom AFB, MA, USA
来源：
Journal of the American Ceramic Society | 1987年 / 70卷 / 07期
关键词：
GLASS MANUFACTURE - Physical Chemistry;
D O I：
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学科分类号：
摘要：
The techniques of scanning electron microscopy, energy dispersive X-ray microanalysis, and dark-field transmission electron microscopy were combined to study the phase stability of CdF//2-LiF-AlF//2-PbF//2 glasses. The selected compositions, presumed to be exceptionally stable exhibited a liquid-liquid immiscibility phase transition; this led to the formation of two amorphous phases consisting of a matrix near the original glass composition and an isolated spherical phase which was richer in CdF//2 and poorer in PbF//2 than the matrix.
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页码：510 / 513
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