Poly(schiff's bases)-bifluorophores: synthesis, photophysical properties, non-radiative energy transfer of electronic excitation

被引:0
|
作者
Siling, S.A. [1 ]
Shamahin, S.V. [1 ]
Ronova, I.A. [1 ]
Kovalevski, A.Y. [1 ]
Grachev, A.B. [1 ]
Tsiganova, O.Y. [1 ]
Yuzhakov, V.I. [1 ]
机构
[1] Inst. of Organo-Element Compounds, Russian Academy of Sciences, Vavilova Street 28, 117813 Moscow, Russia
关键词
Azomethynes - Bifluorophores - Electronic excitation - Nonradiative energy transfer - Photophysical properties - Polyschiffs bases;
D O I
10.1080/00914030108035871
中图分类号
学科分类号
摘要
The method of synthesis of unsymmetrical azomethynes-bifluorophores where one of the fluorescent fragments is a donor of electron excitation energy and the second one is an acceptor was worked out. Photophysical properties of azomethynes-bifluorophores were investigated. It was shown that in these compounds non-radiative energy transfer takes place. It was established that quantum-chemical semiempirical method AM1 may be used for the calculation of spatial structure of amines-fluorophores.
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页码:115 / 130
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