Synthesis of o-Phenylenediamine from o-nitroaniline and H2S in Aqueous Solutions.

被引:0
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作者
Bogdal, Stanislaw
Milewska, Malgorzata
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来源
Przemysl Chemiczny | 1979年 / 58卷 / 09期
关键词
CATALYSTS - Sodium Polysulfides - CHEMICAL REACTIONS - Reduction - SULFUR COMPOUNDS - Applications;
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摘要
In the reported experiments, the investigations of reduction, catalyzed by sodium polysulphides, of o-nitrioaniline with H//2S in water solutions in the presence of emulgator have been carried out. The investigations have shown that in these conditions in the temperature ca. 373 K under the pressure 3,5. 10**5 N/m**2 the process has been relatively quick. The final products of the reduction have been o-phenylenediamine and elementary sulphur.
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页码:481 / 483
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