Calculations of Soave's modification of Benedict-Webb-Rubin equation of state

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Bijedic, M. [1 ]
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[1] Faculty of Technology, 75000 Tuzla, Bosnia and Herzegovina
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An algorithm and program for calculation of equilibrium ratio of vaporization for the mixtures of hydrocarbons, based on Soave's modification of Benedict-Webb-Rubin equation of state (SBWR) was developed. The program was tested by calculation of equilibrium ratios (K-values) for the following mixtures of hydrocarbons: methane/butane, ethane/butane, methane/propane, methane/i-butane, methane/pentane, ethylene/heptane, ethane/heptane, butane/heptane, propane/pentane, methane/ethane/pentane, methane/propane/pentane and methane/ethylene/i-butane under different p and T. The results of calculations were compared with experimental results and with the results obtained by Soave-Redlich-Kwong (SRK) and Peng-Robinson (PR) equations of state.
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页码:217 / 232
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