Effect of deposition temperature and composition on the microstructure and electrical property of SrBi2Ta2O9 thin films prepared by metalorganic chemical vapor deposition

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作者
Nukaga, Norimasa [1 ]
Ishikawa, Katsuyuki [1 ]
Funakubo, Hiroshi [1 ]
机构
[1] Dept. of Innov. and Engineered Mat., Interdisciplinary Graduate School, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan
关键词
Composition effects - Crystal microstructure - Electric field effects - Ferroelectric materials - High temperature effects - Metallorganic chemical vapor deposition - Strontium compounds - Surface roughness - Thin films;
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摘要
SrBi2Ta2O9 (SBT) thin films were prepared by conventional thermal metalorganic chemical vapor deposition (MOCVD) and subsequent heat treatment. The SBT film deposited at 500 °C had a smoother surface and better step coverage than that deposited at 750 °C. The degree of step coverage deposited at 500 °C was 0.82. An almost single phase of SBT was obtained for the film with a Bi/Ta mole ratio of 1.0 by heat treatment at 750 °C for 30 min in O2 atmosphere after MOCVD deposition at 500 °C. 2Pr and EC at an applied electric field of 620 kV/cm were 12.2 μC/cm2 and 87 kV/cm, respectively, when the film was deposited at 500 °C followed by heat treatment at 800 °C for 30 min in O2 atmosphere, and its Bi/Ta ratio was 1.2.
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页码:5428 / 5431
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