HINDERED INTERNAL ROTATION IN N-CYCLOALKYL AMIDES.

被引：0
|
作者：
Nishiyama, Tomihiro
Nagata, Kazui
Yamada, Fukiko
机构：
来源：
Technology Reports of Kansai University | 1983年 / 24期
关键词：
ELECTRONIC PROPERTIES;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Spectrum analysis of eleven N-cycloalkyl amides reveal that three of these, N-cyclopropyl formamide, N-cyclobutyl formamide, and N-cyclopentyl formamide, exist both in the E and Z configurations about the central C-N bond. In the cases of N-cyclohexyl formamide and N-cycloheptyl formamide, the amide moeity did not show the double bond character because of deviation from co-planer.
引用
收藏
页码：159 / 163
相关论文
共 50 条
  • [21] REACTION OF ACYL ISOCYANATES WITH DISUBSTITUTED AMIDES AND AN INVESTIGATION OF HINDERED INTERNAL-ROTATION IN AMIDINE MOLECULES
    ARBUZOV, BA
    AGANOV, AV
    ZOBOVA, NN
    SOFRONOVA, OV
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1977, 26 (02): : 348 - 354
  • [22] RATE PROCESSES AND NUCLEAR MAGNETIC RESONANCE SPECTRA .2. HINDERED INTERNAL ROTATION OF AMIDES
    GUTOWSKY, HS
    HOLM, CH
    JOURNAL OF CHEMICAL PHYSICS, 1956, 25 (06): : 1228 - 1234
  • [23] Internal rotation about the C-N bond of amides
    Kang, YK
    Park, HS
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2004, 676 (1-3): : 171 - 176
  • [24] HINDERED ROTATION AROUND THE C-N BOND IN ADAMANTYLCARBOXYLIC ACID-AMIDES
    MOROZOV, PA
    MOROZOVA, NK
    ILYASOV, AV
    JOURNAL OF STRUCTURAL CHEMISTRY, 1983, 24 (06) : 931 - 931
  • [25] NMR STUDIES OF HINDERED INTERNAL ROATATION IN HIGHER N,N-DIALKYL-AMIDES AND THIONAMIDES
    SIDDALL, TH
    STEWART, WE
    APPLIED SPECTROSCOPY, 1971, 25 (01) : 147 - &
  • [26] ACUTE TOXICITIES OF N-CYCLOALKYL DERIVATIVES OF NORADRENALONE AND THEIR EFFECTS ON VOLUNTARY LOCOMOTOR ACTIVITY IN MICE
    CHANG, LCT
    COBBIN, LB
    ARCHIVES INTERNATIONALES DE PHARMACODYNAMIE ET DE THERAPIE, 1971, 192 (02): : 279 - &
  • [27] INTERNAL-ROTATION BARRIERS IN N,N-DI(CHLOROMETHYL)AMIDES
    VERESHCHAGIN, AN
    NASYROV, DM
    KLOCHKOV, VV
    POLUSHIN, VB
    AGANOV, AV
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1983, 32 (07): : 1370 - 1372
  • [28] HINDERED INTERNAL ROTATION AND DIELECTRIC RELAXATION
    KLUG, DD
    KRANBUEHL, DE
    VAUGHAN, WE
    JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (11): : 4187 - +
  • [29] HINDERED INTERNAL-ROTATION IN BENZOPHENONE
    GOUGH, KM
    WILDMAN, TA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) : 9141 - 9144
  • [30] HINDERED INTERNAL ROTATION AND ESR SPECTROSCOPY
    STONE, EW
    MAKI, AH
    JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (06): : 1326 - &
12345