Selective oxidative hydroxylation of arylboronic acids by colloidal nanogold catalyzed in situ generation of H2O2 from alcohols under aerobic conditions

被引：0
|
作者：
Vinsen Y.U. [1 ]
Sakurai H. [1 ]
机构：
[1] Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka
来源：
Bulletin of the Chemical Society of Japan | 2020年 / 93卷 / 02期
基金：
日本学术振兴会;
关键词：
Aerobic oxidation; Nanogold catalyst; Solvent effect;
D O I：
10.1246/BCSJ.20190265
中图分类号：
学科分类号：
摘要：
Selective hydroxylation of arylboronic acids was achieved through PVP (polyvinylpyrrolidone)-stabilized nanogold catalyzed in situ generated H2O2 formed by the oxidation of an alcoholic solvent under aerobic conditions. The synthetic application of in situ generated H2O2 was investigated through aerobic epoxidation of (E)-chalcone. © 2020 The Chemical Society of Japan.
引用
收藏
页码：299 / 301
页数：2
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