Economic viability and overall performance analysis of optimized Cu-Fe-ZSM-5 catalyst for NOx and particulate matter removal using NH3-SCR

被引:1
|
作者
Shirke, Shivani [1 ,2 ]
Chou, Feng-Chih [1 ,2 ]
Wang, Yu-Zheng [1 ,2 ]
Lin, Yuan-Chung [1 ,2 ,3 ,4 ]
机构
[1] Natl Sun Yat Sen Univ, Inst Environm Engn, Kaohsiung 804, Taiwan
[2] Natl Sun Yat Sen Univ, Ctr Emerging Contaminants Res, Kaohsiung 804, Taiwan
[3] Natl Sun Yat Sen Univ, Net Zero Emiss & Resource Recycling Technol Res Ct, Kaohsiung 804, Taiwan
[4] Kaohsiung Med Univ, Coll Hlth Sci, Dept Publ Hlth, Kaohsiung 807, Taiwan
关键词
Cu-Fe-ZSM-5; NH3-SCR; Sulphur poisoning; Emission coefficient; Cost-benefit analysis; REDUCTION; OXIDATION; SO2; NITROGEN; OXIDE; NH3;
D O I
10.1016/j.fuel.2024.133435
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The necessity of a broader working temperature range of NH3-SCR catalysts has been considered as the need of the hour to tackle air pollutants like NOx and particulate matter (PM). The catalysts currently being used pose varied difficulties in the form of sulphur poisoning, inadequate temperature range, catalyst regeneration etc. An innovative and economic bimetallic combination of Cu-Fe on ZSM-5 with minimum weight percentage of metals and optimum efficiency has been synthesized in this study. In this research, we further focus on this Cu-Fe combination, to understand its feasibility for commercial applications. This bimetallic combination, used on the self-synthesized zeolite (ZSM-5), showed a consistent NOx removal efficiency of above 90% over the entire test temperature range, when compared with a commercially available zeolite. This Cu-Fe combination catalyst performed outstandingly in resisting sulphur poisoning and had NOx and PM emission coefficients well below the standard emissions control of Taiwan. It showed a good N2 selectivity as well. The study also analyses the costbenefit ratio for the production of this catalyst for industrial applications with an annual net profit of around 14,66,124.09 USD for five parallel units.
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页数:9
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