A highly stretchable, self-healing, self-adhesive polyacrylic acid/chitosan multifunctional composite hydrogel for flexible strain sensors

Conductive hydrogels have emerged as excellent candidates for the design and construction of flexible wearable sensors and have attracted great attention in the field of wearable sensors. However, there are still serious challenges to integrating high stretchability, self-healing, self-adhesion, excellent sensing properties, and good biocompatibility into hydrogel wearable devices through easy and green strategies. In this paper, multifunctional conductive hydrogels (PCGB) with good biocompatibility, high tensile (1694 % strain), self-adhesive, and self-healing properties were fabricated by incorporating boric acid (BA) and glucose (Glu) simultaneously into polyacrylic acid (PAA) and chitosan (CS) polymer networks using a simple one-pot polymerization method. Furthermore, the hydrogel strain sensor constructed from the PCGB assembly had great sensing property including high sensitivity (GF = 5.7), durability and stability (5000 cycles). The hydrogel strain sensor was applied to the detection of human motion, which exhibited accurate detection behavior for both large-scale motions and small activities. A strategy to design and fabricate multifunctional conductive hydrogels integrating high stretchability, self-healing, self-adhesion and good biocompatibility was provided, and the multifunctional conductive hydrogels broadened the application of hydrogel-based wearable sensor. © 2024 Elsevier Ltd