Study on copolymerization of ethylene/1-hexene catalyzed by a novel polystyrene-supported metallocene catalyst

被引：0
|
作者：
Wang, Wenqin [1 ]
Wang, Li [1 ]
Dong, Xiaochen [1 ]
Sun, Tianxu [1 ]
Wang, Jianfeng [1 ]
机构：
[1] State Key Laboratory of Polymer Reaction Engineering, College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China
来源：
Journal of Applied Polymer Science | 2006年 / 102卷 / 02期
关键词：
Ethylene/1-hexene copolymerization was carried out with polystyrene-supported metallocene catalyst. It was found that the kinetic of the copolymerization was strongly influenced by the steric hindrance of carrier. The influences of 1-hexene concentration in the feed on catalyst productivity and comonomer reactivity were investigated. The microstructure of resultant copolymer was an alyzed by 13C NMR. It was found that the different carriers have slight effect on the composite of copolymer. © 2006 Wiley Periodicals; Inc;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：1574 / 1577
相关论文
共 50 条
  • [21] Ethylene/1-Hexene Copolymerization with A Novel SiO2-Supported Inorganic and Organic Hybrid Chromium-based Catalyst
    Zhang, Shiliang
    Cheng, Ruihua
    Dong, Qi
    He, Xuelian
    Wang, Quntao
    Tang, Yan
    Yu, Yongling
    Xie, Kan
    Da, Jianwen
    Terano, Minoru
    Liu, Boping
    MACROMOLECULAR REACTION ENGINEERING, 2013, 7 (06) : 254 - 266
  • [22] A Novel SiO2-Supported Fluorine Modified Chromium-Vanadium Bimetallic Catalyst for Ethylene Polymerization and Ethylene/1-Hexene Copolymerization
    Sun, Qiaoqiao
    Wang, Lisong
    Cheng, Ruihua
    Liu, Zhen
    He, Xuelian
    Zhao, Ning
    Liu, Boping
    MACROMOLECULAR REACTION ENGINEERING, 2017, 11 (05)
  • [23] Study of the effect of the monomer pressure on the copolymerization of ethylene with 1-hexene
    Quijada, R
    Rojas, R
    Mauler, RS
    Galland, GB
    Scipioni, RB
    JOURNAL OF APPLIED POLYMER SCIENCE, 1997, 64 (13) : 2567 - 2574
  • [24] Copolymerization of propene and 1-hexene with isospecific and syndiospecific metallocene catalysts
    Polym. Bull., 4-5 (415-421):
  • [25] Copolymerization of propene and 1-hexene with isospecific and syndiospecific metallocene catalysts
    Kim, I
    Kim, YJ
    POLYMER BULLETIN, 1998, 40 (4-5) : 415 - 421
  • [26] Copolymerization of propylene and 1-hexene in the presence of homogeneous metallocene catalysts
    Rishina, L.A.
    Galashina, N.M.
    Nedorezova, P.M.
    Klyamkina, A.N.
    Aladyshev, A.M.
    Tsvetkova, V.I.
    Baranov, A.O.
    Optov, V.A.
    Kissin, Yu.V.
    Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, 2004, 46 (09): : 1493 - 1504
  • [27] Study on ethylene/1-hexene copolymerization catalyzed by a-diimine nickel catalysts with different ligands
    Xing, Yusheng
    Yu, Haojie
    Wang, Li
    Wang, Nan
    Zhu, Lei
    Liang, Ruixue
    Uddin, Md Alim
    MAGNETIC RESONANCE LETTERS, 2021, 1 (02) : 131 - 141
  • [28] Copolymerization of propene and 1-hexene with isospecific and syndiospecific metallocene catalysts
    Il Kim
    Young Jae Kim
    Polymer Bulletin, 1998, 40 : 415 - 421
  • [29] Copolymerization of propylene and 1-hexene in the presence of homogeneous metallocene catalysts
    Rishina, LA
    Galashina, NM
    Nedorezova, PM
    Klyamkina, AN
    Aladyshev, AM
    Tsvetkova, VI
    Baranov, AO
    Optov, VA
    Kissin, YV
    POLYMER SCIENCE SERIES A, 2004, 46 (09) : 911 - 920
  • [30] Effect of internal electron donor on copolymerization of ethylene and 1-hexene catalyzed by supported Ziegler-Natta catalysts
    Zhang, Letian
    Fan, Zhiqiang
    Fu, Zhisheng
    E-POLYMERS, 2008,
12345