Biobased interpenetrating polymers networks derived from oligomerized soybean oil and polydimethylsiloxane

被引：0

作者：

机构：

[1] Dewasthale, Sudhanwa

[2] Graiver, Daniel

[3] Narayan, Ramani

来源：

Narayan, Ramani | 1600年 / John Wiley and Sons Inc卷 / 132期

关键词：

A series of interpenetrating polymer networks (IPNs) with different compositions were prepared from silylated oligomerized soybean oil and silanol-terminated polydimethylsiloxane. Oligomerization of soybean oil was achieved by heating it with a catalyst in a Parr reactor at elevated temperatures. Vinyltrimethoxysilane was then grafted onto the oligomerized oil. Crosslinked films were obtained from solutions as the silanol groups between the two immiscible components condensed to form stable siloxanes linkages resulting in an entangled network characterized by microphase separation typical to IPNs. The crosslink density between the dispersed phase and the continuous phase was calculated from the average particle size of the dispersed phase. The mechanical and thermal properties were also studied and were found to be directly related to the composition and the crosslink density. These IPN resins can be used as high release liners; low friction materials; soft-feel coatings or as convenient one-package protective coatings. © 2014 Wiley Periodicals; Inc; J; Appl; Polym; Sci; 2015; 132; 41709. © 2014 Wiley Periodicals;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

引用

共 50 条

[41] Biobased Low-k Polymers at High Frequency Derived from Isoeugenol
Liu, Fengping
Fang, Qiang
Sun, Jing
ACS APPLIED POLYMER MATERIALS, 2022, 4 (10) : 7173 - 7181
[42] Renewable polymers derived from ferulic acid and biobased diols via ADMET
Barbara, Imane
Flourat, Amandine L.
Allais, Florent
EUROPEAN POLYMER JOURNAL, 2015, 62 : 236 - 243
[43] Vernonia oil-based acrylate and methacrylate polymers and interpenetrating polymer networks with epoxy resins
Kolot, V
Grinberg, S
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 91 (06) : 3835 - 3843
[44] Evaluation of adhesion and corrosion wear resistance of biobased polymers derived from linseed oil deposited on Fe- Zn sheets
Tello-Gonzalez, Jorge
Hernandez-Lopez, Susana
Vigueras-Santiago, Enrique
Gonzalez-Martinez, David A.
Martinez-Barrera, Gonzalo
INGENIERIA Y COMPETITIVIDAD, 2023, 25 (01):
[45] Preparation of fully biobased epoxy resins from soybean oil based amine hardeners
Frias, Celia F.
Serra, Armenio C.
Ramalho, A.
Coelho, Jorge F. J.
Fonseca, Ana C.
INDUSTRIAL CROPS AND PRODUCTS, 2017, 109 : 434 - 444
[46] Assessment of Epoxidized Isobutyl Fatty Esters from Soybean Oil Distillates as Biobased Plasticizers
Najera, Laura N.
Orjuela, Alvaro
Narvaez-Rincon, Paulo Cesar
Sanchez-Nacher, Lourdes
Montanes, Nestor
Quiles-Carrillo, Luis
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2024, 63 (50) : 22203 - 22219
[47] Novel biobased resins from blends of functionalized soybean oil and unsaturated polyester resin
Miyagawa, Hiroaki
Mohanty, Amar K.
Burgueno, Rigoberto
Drzal, Lawrence T.
Misra, Manjusri
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2007, 45 (06) : 698 - 704
[48] Polymers from renewable resources. XXV. Interpenetrating polymer networks derived from castor oil isophorone diisocyanate cardanyl acrylate cardanyl methacrylate: Thermal and XRD studies
Das, D
Nayak, PL
Lenka, S
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 1998, 37 (04) : 419 - 426
[49] Polymers from renewable resources. XXIX. Synthesis and characterization of interpenetrating networks derived from castor-oil-based polyurethane-4-acetyl phenyl methacrylate
Das, SK
Lenka, S
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 1999, 38 (01) : 149 - 157
[50] Polymers from renewable resources .14. Interpenetrating polymer networks derived from castor oil - Isophorone diisocyanate-polyacrylamide: Thermal, scanning electron microscopy, and XRD studies
Mishra, DK
Das, SK
Nayak, SS
Nayak, PL
Lenka, S
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1996, A33 : 423 - 429

← 1 2 3 4 5 →