Microstructure and mechanical properties of TaNbTiZr refractory high-entropy alloy fabricated by EBM

被引:0
|
作者
Xie Z. [1 ]
Fu A. [1 ]
Wang J. [1 ]
Wang X. [1 ,2 ]
Cao Y. [1 ]
Liu B. [1 ]
Liu Y. [1 ]
机构
[1] State Key Laboratory for Powder Metallurgy, Central South University, Changsha
[2] Xi’an Sailong Additive Technology Co., Ltd., Xi’an
基金
中国国家自然科学基金;
关键词
mechanical property; microstructure; refractory high-entropy alloy; selective electron beam melting;
D O I
10.11817/j.ysxb.1004.0609.2023-44566
中图分类号
学科分类号
摘要
Refractory high-entropy alloys (RHEAs) exhibit excellent high-temperature performance and have broad application prospects in aerospace, nuclear energy, and other fields. However, it is difficult to prepare RHEAs through conventional manufacturing methods because of the high melting points of the constituent elements. In this study, high-quality TaNbTiZr RHEA spherical powders prepared by plasma rotating electrode process (PREP) were used as raw materials to fabricate the TaNbTiZr RHEA by electron beam melting (EBM). The effects of process parameters on the microstructure and mechanical properties were investigated by orthogonal experiments. The results show that the density of the EBMed samples increase initially and then decrease with the increase of energy density, and the EBMed sample at an energy density of 37.5 J/m has the highest relative density of 98%. The TaNbTiZr RHEA consists of fine equiaxed grains on both the XOY and XOZ planes, with average grain sizes of 6.32 μm and 6.93 μm, respectively. There are (Nb, Ta)-rich BCC1 matrix phase and Zr-rich BCC2 network phase inside the grains. The TaNbTiZr RHEA exhibits excellent mechanical properties, with yield strength, tensile strength, and elongation of 988 MPa, 1173 MPa, and 3.99%, respectively. Theoretical calculation shows that the high yield strength of the TaNbTiZr RHEA is mainly due to the effects of high lattice distortion strengthening and high grain boundary strengthening. © 2024 Central South University of Technology. All rights reserved.
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页码:1179 / 1189
页数:10
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共 34 条
  • [21] XIA M, CHEN Y, CHEN K, Et al., Synthesis of WTaMoNbZr refractory high-entropy alloy powder by plasma spheroidization process for additive manufacturing, Journal of Alloys and Compounds, 917, (2022)
  • [22] KOK Y, TAN X, TOR S, Et al., Fabrication and microstructural characterisation of additive manufactured Ti-6Al-4V parts by electron beam melting, Virtual and Physical Prototyping, 10, 1, (2015)
  • [23] LUO X, YANG C, FU Z Q, Et al., Achieving ultrahigh-strength in beta-type titanium alloy by controlling the melt pool mode in selective laser melting, Materials Science and Engineering A, 823, (2021)
  • [24] JUAN C, TSAI M, TSAI C, Et al., Simultaneously increasing the strength and ductility of a refractory high-entropy alloy via grain refining[J], Materials Letters, 184, pp. 200-203, (2016)
  • [25] XIAO B, JIA W, TANG H, Et al., Microstructure and mechanical properties of WMoTaNbTi refractory high-entropy alloys fabricated by selective electron beam melting[J], Journal of Materials Science & Technology, 108, (2022)
  • [26] GOU S, GAO M, SHI Y, Et al., Additive manufacturing of ductile refractory high-entropy alloys via phase engineering, Acta Materialia, 248, (2023)
  • [27] LI Z, LAI W, TONG X, Et al., Design of TiZrNbTa multiprincipal element alloys with outstanding mechanical properties and wear resistance, Materials Science and Engineering A, 845, (2022)
  • [28] MA Y X, ZHANG Y, ZHANG Z W, Et al., Two novel Zr-rich refractory high-entropy alloys with excellent tensile mechanical properties, Intermetallics, 157, (2023)
  • [29] WU Y D, CAI Y H, WANG T, Et al., A refractory Hf<sub>25</sub>Nb<sub>25</sub>Ti<sub>25</sub>Zr<sub>25</sub> high-entropy alloy with excellent structural stability and tensile properties, Materials Letters, 130, (2014)
  • [30] XU Z Q, MA Z L, TAN Y, Et al., Designing TiVNbTaSi refractory high-entropy alloys with ambient tensile ductility, Scripta Materialia, 206, (2022)