A Polyoxotungstate Stabilized Copper Catalyst for Green and Efficient Transformation of Alcohols to Ketones

被引：0
|
作者：
Wei, Zheyu [1 ]
Yang, Guoping [1 ,2 ]
Wei, Yongge [1 ,3 ]
机构：
[1] Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing,100084, China
[2] Jiangxi Province Key Laboratory of Functional Organic Polymers, School of Chemistry and Materials Science, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang,330013, China
[3] State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing,100191, China
来源：
European Journal of Inorganic Chemistry | 2024年 / 27卷 / 30期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1002/ejic.202400424
中图分类号：
学科分类号：
摘要：
A water-soluble copper catalyst (NH4)8[Cu2(H2O)8W12O42] ⋅ 4H2O is prepared by the generated paratunngstate B in situ, which can catalyze the H2O2 oxidation of cyclohexanol to cyclohexanone with a yield above 98 % in water under much milder conditions of 35 °C and atmospheric pressure, and the substrate can be extend to other secondary alcohols, potentially leading to an economical, green, and efficient ketone production method for industrial use. © 2024 Wiley-VCH GmbH.
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