Surface modification of imide containing polymers I: Catalytic groups

被引：0
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作者：
Verdianz, Thomas [1 ]
Simbürger, Horst [2 ]
Liska, Robert [1 ]
机构：
[1] Institute of Applied Synthetic Chemistry, Division of Macromolecular Chemistry, Vienna University of Technology, Getreidemarkt 9/163/MC, 1060 Vienna, Austria
[2] ELIN EBG Motoren GmbH, Elingasse 3, 8160 Weiz, Austria
来源：
European Polymer Journal | 2006年 / 42卷 / 03期
关键词：
This paper describes basic studies of the surface modification of polyimide covered wires for insulation of electrical machines. Drain-off of the impregnating resin during production should be reduced by introduction of surface catalytic groups. 1H NMR kinetic analysis of aminolytic ring opening reaction of low molecular model compounds for polyimides showed very fast modification reactions. The catalytic effect of various functional groups on unsaturated polyester imide; acrylate and epoxy resins was investigated by DSC. Co(II)-catalysts and tertiary aliphatic amines proved highest activity for double bond containing systems and epoxy resins; respectively. Aminolytic treatment of Kapton&reg slides was followed by ATR-IR spectroscopy. Plate-plate rheometer measurements of epoxy resins employing tertiary amine-treated Kapton&reg slides proved significantly reduced gelling temperature. © 2005 Elsevier Ltd. All rights reserved;
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页码：638 / 654
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